Multi-nuclear, high-pressure, <i>operando</i> FlowNMR spectroscopic study of Rh/PPh<sub>3</sub> – catalysed hydroformylation of 1-hexene
نویسندگان
چکیده
The hydroformylation of 1-hexene with 12 bar 1 : H2/CO in the presence catalytic system [Rh(acac)(CO)2]/PPh3 was successfully studied by real-time multinuclear high-resolution FlowNMR spectroscopy at 50 °C.
منابع مشابه
Hydroformylation of 1-Hexene over Rh/Nano-Oxide Catalysts
The effect of nanostructured supports on the activity of Rh catalysts was studied by comparing the catalytic performance of nanoand bulk-oxide supported Rh/ZnO, Rh/SiO2 and Rh/TiO2 systems in 1-hexene hydroformylation. The highest activity with 100% total conversion and 96% yield of aldehydes was obtained with the Rh/nano-ZnO catalyst. The Rh/nano-ZnO catalyst was found to be more stable and ac...
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ژورنال
عنوان ژورنال: Faraday Discussions
سال: 2021
ISSN: ['1359-6640', '1364-5498']
DOI: https://doi.org/10.1039/c9fd00145j